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Chemical Abstracts Service (CAS) has created a quick slideshow on key features of SciFinder's search interface.
CAS also creates SciFinder tutorials, some of which focus on specific database functions, for example:
Drawing Editor - Introduction
Search by Exact Structure
Searching for References [pdf]
Reference Searching [ video]
Working with References [pdf]
More tutorials are stored on the CAS Training page.
The CAS training materials usually consist of self-paced slideshows or videos.